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Details for article 3 of 10 found articles
| Title: |
An Apparatus for the Determination of Rates of Proton Transfer and Other Very Fast Reactions |
| Author: |
Staples†, Bert R. Turner‡, David J. Atkinson, Gordon |
| Appeared in: |
Instrumentation science & technology |
| Paging: | Volume 2 (1969) nr. 2 pages 127-147 |
| Year: |
1969 |
| Contents: |
An apparatus designed to study the kinetics of very fast reactions, such as proton transfer, using an electric field jump (E-jump) relaxation technique is described. A 10-kV square wave pulse with a pulse duration of 3 μsec is used as the perturbing force. The increase in degree of dissociation of a dilute solution of a weak electrolyte can be followed directly upon application of the pulse. Secondary effects are canceled out by means of a suitable difference method in which the difference in signals is analyzed by a differential amplifier and displayed as an oscilloscope trace. Relaxation times on the order of 10-7 sec, yielding second-order rate constants of 1010 liter mole-1 sec-1, can be investigated by this method. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 3 of 10 found articles
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