Synthesis, characterization and semiempirical calculations of mercury(II) complexes of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine
Titel:
Synthesis, characterization and semiempirical calculations of mercury(II) complexes of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine
Auteur:
El-Qisairi, Arab K.
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 60 (2007) nr. 10 pagina's 1069-1076
Jaar:
2007
Inhoud:
The reactions of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine (bptz) with HgX2 (X = Cl, Br, I) have been investigated. The isolated complexes have been characterized by elemental analysis, conductivity measurements, IR, 1H, and 13C NMR spectroscopy. PM3 calculations show that the trans-conformation is preferred. Thermodynamic calculations and orbital energies are reported.
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