Synthesis, characterization and semiempirical calculations of mercury(II) complexes of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine
Title:
Synthesis, characterization and semiempirical calculations of mercury(II) complexes of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine
Author:
El-Qisairi, Arab K.
Appeared in:
Journal of coordination chemistry
Paging:
Volume 60 (2007) nr. 10 pages 1069-1076
Year:
2007
Contents:
The reactions of 3,6-bis(2'-pyridyl)-1,2,4,5-tetrazine (bptz) with HgX2 (X = Cl, Br, I) have been investigated. The isolated complexes have been characterized by elemental analysis, conductivity measurements, IR, 1H, and 13C NMR spectroscopy. PM3 calculations show that the trans-conformation is preferred. Thermodynamic calculations and orbital energies are reported.
Journal description