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Details for article 7 of 19 found articles
| Title: |
Oxidation of a stable 1,3-diborata-2,4-diphosphonio-cyclobutane-1,3-diyl |
| Author: |
Fuks, Gad Donnadieu, Bruno Sacquet, Alix Maron, Laurent Bourissou, Didier Bertrand, Guy |
| Appeared in: |
Main group chemistry |
| Paging: | Volume 9 (2010) nr. 1-2 pages 101-109 |
| Year: |
2010-03-28 |
| Contents: |
According to cyclic voltammetry, the stable 1,3-diborata-2,4-diphosphonio-cyclobutane-1,3-diyl 1 can be readily oxidized. The oxidation is irreversible, preventing the characterization of the corresponding radical cation, whose structure has been investigated by DFT calculations. Diradicaloid 1 is oxidized by silver salts AgX (X=Cl, OTf), to give silver mirror along with the bis(chloride) and bis(trifluoromethane sulfonate) adducts 2 and 3. |
| Publisher: |
IOS Press |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 7 of 19 found articles
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