Preparation of 2,4,6-trisphosphinyl-1,3,5-triazine (1,3,5-triazinetriphosphonic acid)
Titel:
Preparation of 2,4,6-trisphosphinyl-1,3,5-triazine (1,3,5-triazinetriphosphonic acid)
Auteur:
Ioannou, Panayiotis V.
Verschenen in:
Main group chemistry
Paginering:
Jaargang 13 (2014) nr. 2 pagina's 147-151
Jaar:
2014-05-22
Inhoud:
The reaction of excess tris(trimethylsilyl) phosphite with cyanuric chloride produced the ester 2,4,6-trisdi(trimethylsilyloxyphosphinyl)-1,3,5-triazine. After partial purification the ester was methanolysed to the free acid 2,4,6-trisphosphinyl-1,3,5-triazine in good to excellent yields. Some properties of the acid are described.
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