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| Titel: |
Formation of binary ion clusters from polar vapours: effect of the dipole-charge interaction |
| Auteur: |
A. B. Nadykto F. Yu |
| Verschenen in: |
Atmospheric chemistry and physics |
| Paginering: | Jaargang 4 (2004) nr. 2 pagina's 385-389 |
| Jaar: |
2004 |
| Inhoud: |
Formation of binary cluster ions from polar vapours is considered. The effect of vapour polarity on the size and composition of the critical clusters is investigated theoretically and a corrected version of classical Kelvin-Thomson theory of binary ion-induced nucleation is derived. The model predictions of the derived theory are compared to the results given by classical binary homogeneous nucleation theory and ion-induced nucleation theory. The calculations are performed in wide range of the ambient conditions for a system composed of sulfuric acid and water vapour. It is shown that dipole-charge interaction significantly decreases the size of the critical clusters, especially under the atmospheric conditions when the size of critical clusters is predicted to be small. |
| Uitgever: |
Copernicus GmbH (provided by DOAJ) |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 5 van 23 gevonden artikelen
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