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                                       Details for article 1 of 65 found articles
 
 
  A FIRST-DERIVATIVE METHOD TO EVALUATE THE KINETIC PARAMETERS FROM TRANSIENTS OF CATALYTIC IGNITION ON PLATINUM WIRES
 
 
Title: A FIRST-DERIVATIVE METHOD TO EVALUATE THE KINETIC PARAMETERS FROM TRANSIENTS OF CATALYTIC IGNITION ON PLATINUM WIRES
Author: O.M. Staicu
V. Munteanu
Domnina Razus
D. Oancea
Appeared in: Analele Universitatii Bucuresti. Chimie
Paging: Volume XVI (2007) nr. II pages 85-91
Year: 2007
Contents: The transient period for the catalytic combustion on isothermally heated platinum wires at high temperatures, described by a three parameter kinetic equation, can be conveniently exploited for the evaluation of the activation parameters using the first-derivative with respect to time of the chemical heat flow rate, an experimentally accessible property. The first-derivative curve has only two parameters, containing the essential information regarding the diffusion and reaction steps. The results obtained by this method agree very well with those reported from a nonlinear regression analysis of the integral equation, for the catalytic combustion of n-butane/air stoichiometric mixture.
Publisher: Ars Docendi Publishing House (provided by DOAJ)
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

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