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Details for article 115 of 143 found articles
| Title: |
SYNTHESIS, SPECTROSCOPIC AND MAGNETIC CHARACTERISATION OF SOME NICKEL(II) COMPLEXES WITH 2-AMINO-1,3,4-THIADIAZOLE-5-THIOL |
| Author: |
Rodica Olar Mihaela Badea Nicolae Stanica Elena Cristurean Dana Marinescu Ana Emandi |
| Appeared in: |
Analele Universitatii Bucuresti. Chimie |
| Paging: | Volume XIII (2004) nr. I-II pages 185-190 |
| Year: |
2004 |
| Contents: |
A series of complexes of Ni(II) with 2-amino-1,3,4-thiadiazole-5-thiol (HTDA) havebeen synthesised and characterised. The bonding and stereochemistry of the complexes havebeen characterised by IR and electronic studies, magnetic susceptibility at room temperature andconductivity measurements. The Ni(II) complexes exhibit octahedral or trigonal bipyramidalstereochemistry. Thiadiazole in monoanionic form is coordinated as chelate through cyclicnitogen (N4) and exocyclic sulfur of the tioamide moiety while in neutral form acts as unidentatethrough N4. The effective magnetic moments at room temperature agree with proposedstereochemistry. Data concerning thermal behaviour of complex [Ni(TDA)Cl(H2O)3]ยท2H2O arepresented. |
| Publisher: |
Ars Docendi Publishing House (provided by DOAJ) |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 115 of 143 found articles
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