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Details van artikel 18 van 21 gevonden artikelen
| Titel: |
POLYMERIZATION OF DIFFERENT LIGNINS BY LACCASE |
| Auteur: |
Maija-Liisa Mattinen Tapani Suortti Richard Gosselink Dimitris S. Argyropoulos Dmitry Evtuguin Anna Suurnäkki Ed de Jong Tarja Tamminen |
| Verschenen in: |
BioResources |
| Paginering: | Jaargang 3 (2008) nr. 2 pagina's 549-565 |
| Jaar: |
2008 |
| Inhoud: |
In this study the oxidative polymerization of different lignins, i.e. Flax Soda lignin, Spruce EMAL, and Eucalyptus Dioxane lignin by Trametes hirsuta laccase was compared. Initially the structures of the different lignins were compared by Fourier transform infrared spectroscopy. The reactivity of laccase with the different types of lignins in the absence of mediators was examined and verified by oxygen consumption measurements. The molecular weight distributions of treated and untreated lignins were determined by two different size exclusion chromatography methods. Furthermore, the potential of matrix-assisted laser desorption/ionisation-time of flight-mass spectroscopy for determination of the absolute molecular weights of the different lignins was evaluated. The data showed that all the technical lignins could be activated and polymerized by laccase to different degrees. The efficiency as indicated by measurements of the degree of polymerization was found to increase in the order of Spruce EMAL < Eucalyptus Dioxane lignin < Flax Soda lignin. Overall, this data supplies foundations for using enzymes more efficiently in the enzymatic upgrading of lignin. |
| Uitgever: |
College of Natural Resources, North Carolina State University |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 18 van 21 gevonden artikelen
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