Determination of permeation parameters of experimental PET films coated with SiO x to ethyl acetate, oxygen and water vapour
Title:
Determination of permeation parameters of experimental PET films coated with SiO x to ethyl acetate, oxygen and water vapour
Author:
Adamantiadi, A. Badeka, A. Kontominas, M. G.
Appeared in:
Food additives and contaminants. Pt. A, Chemistry, analysis, control, exposure & risk assessment
Paging:
Volume 18 (2001) nr. 11 pages 1046-1054
Year:
2001-11-01
Contents:
The permeation parameters of conventional PET films, films coated with SiO x and SiO x -coated films laminated to LDPE were determined for ethyl acetate using the permeation cell/gas chromatography method. Permeation to O 2 and water vapour was also determined to monitor overall changes in the barrier properties of the experimental films. Coating of the PET film was achieved by a 'directed evaporation' method that increased the yield of the coating process from 30-35 to > 70%. It was shown that the SiO x coating increased the film barrier to ethyl acetate by ~ 20-30 times. Permeation values showed low reproducibility, indicating the need for further development and standardization of the 'directed evaporation' web-coating process. The barrier to oxygen and water vapour increased by 20-25 and 12-14 times respectively after coating. The web-coating speed did not seem to influence the barrier properties of the films. Permeation coefficients, diffusion coefficients and solubility coefficients were calculated for all samples.