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  Thermal and mechanical characteristics of polylactide filaments drawn at different temperatures
 
 
Titel: Thermal and mechanical characteristics of polylactide filaments drawn at different temperatures
Auteur: Solarski, Samuel
Ferreira, Manuela
Devaux, Eric
Verschenen in: The journal of the Textile Institute
Paginering: Jaargang 98 (2007) nr. 3 pagina's 227-236
Jaar: 2007
Inhoud: Polylactide (PLA) filaments produced by melt spin-drawing in different conditions (draw ratio, temperature of the draw roll) have been studied to demonstrate the influence of the process conditions on the tensile properties of the PLA filaments. Draw ratio varies from 2 to 3.5 and temperature of the draw roll from 80°C to 120°C. The thermal characteristics have been investigated using modulated differential scanning calorimetry (MDSC) and crystallinity using X-Ray Diffraction (XRD). Shrinkage of PLA multifilaments depending on the processing conditions is also investigated. It is demonstrated that the temperature of the draw roll is essential to obtain PLA filaments with optimum properties. At 80°C, the size of the lamellar crystals, measured using DRX, is not the highest. It is necessary to set the temperature of the draw roll at 110°C to obtain thick lamellar crystals. So, in those conditions, the PLA filaments have their optimum mechanical properties.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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