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Details for article 2 of 20 found articles
| Title: |
Anisotropy of molecular reorientation and geometrical information as determined from short and long range 13C-1H spin cross-relaxation rates |
| Author: |
MUTZENHARDT, P. WALKER, O. CANET, D. HALOUI, E. FURO, I. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 94 (1998) nr. 3 pages 565-569 |
| Year: |
1998-06-20 |
| Contents: |
This study deals with all available 13C-1H cross-relaxation rates in a rigid medium size molecule including short range (one bond) and remote (long range) dipolar interactions. They are obtained by the heteronuclear Overhauser effect spectroscopy (HOESY) experiment modified in such a way that correlations between equivalent sites becomes accessible. It is shown that the whole set of data provides not only the three rotational diffusion elements characterizing a fully anisotropic reorientation but also some interatomic distances which can be compared with those determined from quantum chemistry calculations and/or from crystallographic data. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 2 of 20 found articles
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