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Details for article 14 of 24 found articles
| Title: |
Molecular orbital description of the ligand-field spectra of some tetrahalogeno anions |
| Author: |
Daul, C. Day, P. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 34 (1977) nr. 6 pages 1707-1716 |
| Year: |
1977-12 |
| Contents: |
A MO-based model [1] has been used to describe the ligand-field spectra of the tetrahedral ions MX42- (M = Ni, Co, Fe, Mn and X = Cl, Br, I). Independent assignments of the ligand-field spectra of the latter ions are obtained from published work [1-8]. The energies of the spin-orbit baricentres of the ligand-field transitions are calculated as functions of two orbital population parameters and the energy separations between the e and t2 MO's. From the least-squares analysis of the independently assigned experimental spectra, empirical values of these three parameters are extracted. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 14 of 24 found articles
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