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Details for article 12 of 14 found articles
| Title: |
The molecular hamiltonian |
| Author: |
Howard, B. J. Moss, R. E. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 19 (1970) nr. 4 pages 433-450 |
| Year: |
1970-10 |
| Contents: |
A complete hamiltonian for a translating, rotating, vibrating molecule in the presence of a constant external electromagnetic field is derived starting with the Breit equation reduced to a non-relativistic form, correct to order c-2. A number of new terms appear, which have not been obtained in less precise derivations. These include mass polarization corrections to the orbital Zeeman, spin-orbit and orbit-orbit interactions together with spin-vibration, orbit-vibration and orbit-rotation interactions. In addition there is a vibrational Zeeman interaction which in certain circumstances may be of the same order of magnitude as rotational Zeeman terms. The final hamiltonian provides a starting point for future investigations of the possible effects of these new interactions on the microwave and radiofrequency spectra of both open and closed-shell molecules. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 12 of 14 found articles
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