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Details for article 6 of 14 found articles
| Title: |
Intensities of d-d transitions in the tetrachloroferrate(III) anion |
| Author: |
Balt, S. |
| Appeared in: |
Molecular physics |
| Paging: | Volume 14 (1968) nr. 3 pages 233-239 |
| Year: |
1968 |
| Contents: |
The relative intensities of the d-d bands in the visible spectrum of the tetrachloroferrate(III) ion have been calculated in a semi-empirical MO model in which it has been assumed that all intensity of the spin-forbidden bands has been borrowed from the two lowest-energy charge-transfer bands via direct spin-orbit coupling of the charge-transfer upper states and the metal 4Γ states. The prominence of the 4E(4D) band is reproduced especially well in the calculations. A comparison of the intensity of this band and the first charge-transfer band gives a rather realistic value for the π-antibonding MO eigen vector. The observed intensities of the ions FeCl4- and FeBr4- could also be related in a satisfactory way. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 6 of 14 found articles
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