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Details for article 24 of 37 found articles
| Title: |
On the symmetry of the xyz vibration in the photochemistry of Pt(II) D4h complexes |
| Author: |
Gorller-walrand, Christiane |
| Appeared in: |
Molecular physics |
| Paging: | Volume 102 (2004) nr. 11-12 pages 1361-1365 |
| Year: |
2004-06-10 |
| Contents: |
A symmetry concept is proposed that links the presence of vibronic structure in UV-visible spectra in d-systems, with the identification of a single photochemical reaction pathway. It is shown that the vibronic structure on some bands of the Pt(II) D4h complexes is due to the non- degenerate, ungerade b1u (xyz) vibration that points on an intramolecular twisting process for the photochemical cis-trans isomerization. The reaction coordinate is unambiguously defined in a coordinate system where x and y bisect the metal-ligand ML2 angle. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 24 of 37 found articles
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