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                                       Details for article 3 of 15 found articles
 
 
  Effect of photoreactivity of polyimide on the molecular orientation of liquid crystals on photoreactive polymer/polyimide blends
 
 
Title: Effect of photoreactivity of polyimide on the molecular orientation of liquid crystals on photoreactive polymer/polyimide blends
Author: Sung, Shi-Joon
Lee, Jaemin
Cho, Ki-Yun
Kim, Won Sun
Hah, Hyundae
Shim, Hong-Ku
Park, Jung-Ki
Appeared in: Liquid crystals
Paging: Volume 31 (2004) nr. 12 pages 1601-1611
Year: 2004-12
Contents: We prepared blend alignment layers from polymethacrylate with coumarin side chains (PMA-g-coumarin) and polyimides for the orientation of liquid crystals (LCs) using linearly polarized ultraviolet (UV) irradiation. We used two different polyimides, namely 4,4'-(hexafluoro-isopropylidene) diphthalic anhydride-3,5-diamino-benzoic acid (6FDA-DBA) and pyromellitic dianhydride-4,4'-oxydianiline (PMDA-ODA). It was found that the molecular orientation of the LC depended on the type of polyimide in the blend alignment layer. The thermal stability of the LC orientation was enhanced regardless of the type of polyimide, while the direction of LC orientation was different for each type of polyimide. The photoreactivity of the polyimide was a very important factor in determining the molecular orientation of the LC on the blend alignment layer. This may be attributed to the different mechanisms of LC orientation on PMA-g-coumarin and polyimide induced by the polarized UV irradiation. The direction of the LC orientation could be changed by controlling the photoreaction of the polyimides using the appropriate UV filter for the polarized UV irradiation.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details for article 3 of 15 found articles
 
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