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Details for article 5 of 5 found articles
| Title: |
Reaction of p-Hydroxycinnamyl Alcohols with Transition Metal Salts. 1. Oligolignols and Polylignols (DHPs) From Coniferyl Alcohol |
| Author: |
Landucci, Lawrence L. |
| Appeared in: |
Journal of wood chemistry and technology |
| Paging: | Volume 15 (1995) nr. 3 pages 349-368 |
| Year: |
1995-08-01 |
| Contents: |
Treatment of coniferyl alcohol with iron, cobalt, or manganese salts gave a variety of oligolignols and polylignols (DHPs). Conditions could be adjusted to favor high or low molecular weight products and to give different inter-unit linkage distributions. Oxidation with iron and manganese salts generally gave structures containing β-O-4, β-5, and β-β linkages. Oxidation with iron and manganese salts under highly alkaline conditions also generated α-O-4 structures. The cobalt salt K3Co(CN)6 was unique in that a novel β-γ linkage was generated in high yield. Reactions in the absence of solvent also resulted in the formation of oligolignols and DHPs. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 5 of 5 found articles
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