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| Titel: |
Reactivities of Guaiacyl and Syringyl Lignin Model Phenols Towards Oxidation with Oxygen-Alkali |
| Auteur: |
Sultanov, Vagif S. Wallis, Adrian F. A. |
| Verschenen in: |
Journal of wood chemistry and technology |
| Paginering: | Jaargang 11 (1991) nr. 3 pagina's 291-305 |
| Jaar: |
1991-09-01 |
| Inhoud: |
A range of guaiacyl and syringyl lignin model phenols was treated with oxygen in 1M potassium hydroxide solution at 70°C. The reactions were monitored by high performance liquid chromatography and gas chromatography-mass spectrometry. The reactions of the phenols, which followed pseudo-first-order kinetics, were faster for syringyl than for guaiacyl phenols. For the various 4-substituted syringols the reactivities were in decreasing order CH2-syringyl > CHOH-CH3 π C3H7n > CH2OH > COOH > CHO > CO-CH3. Reaction of 1-guaiacylpropane in 1M potassium hydroxide with oxygen gave products of oxidative scission of the aromatic ring and no dehydrodimer, whereas at pH 11.5 some dehydrodimer was among the reaction products. Vanillyl alcohol and syringyl alcohol yielded vanillin and syringaldehyde, respectively, as minor oxidation products. However, the reaction sites for the series of phenols were generally the aromatic rings rather than the side-chains. Oxidation of alkaline solutions of the phenols with oxygen at 1.0 MPa pressure and 110 and 150°C gave similar mixtures of acids and hydroxyacids. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
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