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Details for article 6 of 13 found articles
| Title: |
Ion Association and Proton Exchange Studies of Mixed Ligand Co(III) Complexes of N,N -Bis(Carboxymethyl)Glycine as Studied by Nuclear Magnetic Resonance Spectroscopy |
| Author: |
Chatterjee, Chinmay Phulambrikar, Alka Das, Subroto |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 21 (1990) nr. 3 pages 231-236 |
| Year: |
1990 |
| Contents: |
Monodiamine (1,2-diaminoethane, 1,2-diaminopropane or 1,3-diaminopropane) and dinitro Co(III) complexes with N,N -bis(carboxymethyl)glycine (H3nta) have been prepared and characterized by electronic, IR and 1H NMR spectroscopy. The association of amine protons with chloride ions and pyridine-d5 and their relative exchange rates in situ have been studied by 1H NMR spectroscopy. The stereoselective approach of the anion at the amine centre is found to dominate ion association and proton exchange processes. Present experimental results offer information as regards the three dimensional structure of the complexes in solution. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 6 of 13 found articles
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