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Details for article 14 of 14 found articles
| Title: |
Ruthenium Carbonyl Complexes of N-Heterocyclic Molecules. Part 2. Preparation, Protonation and Decarbonylation Reactions of Complexes with a Bidentate Terpyridyl Ligand. Structure of [Ru(CO)2(phen)(tpyH)](BF4)3 |
| Author: |
Thomas, Nicholas C. Fischer, Jean |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 21 (1990) nr. 2 pages 119-128 |
| Year: |
1990 |
| Contents: |
The complexes Ru(CO)2(CF3SO3)2(bidentate) {bidentate = 2,2'-bipyridyI (bpy) or 1,10-phenanthroline (phen)} react with 2,2':6',2''-terpyridyl (tpy) forming octahedral [Ru(CO)2(bidentate)(tpy)]2 + compounds (II) which contain a bidentate tpy. Complex II (bidentate = phen) can be protonated to give [Ru(CO)2-(phen)(tpyH)](BF4)3, the structure of which has been established by X-ray crystallography. Treatment of II with trimethylamine N-oxide in methanol at room temperature gives the monocarbonyl compounds [Ru(CO)(bidentate)(tpy)]2+ (IV) which contain a tridentate tpy. Complex IV is also obtained by photolysis of II. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 14 of 14 found articles
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