SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR, BRIDGED COMPLEXES OF THE TYPE LxM(NCSe)2M'(SCN)2L'2
Titel:
SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR, BRIDGED COMPLEXES OF THE TYPE LxM(NCSe)2M'(SCN)2L'2
Auteur:
Singh, P. P. Gupta, A. K. Srivastava, A. K.
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 10 (1980) nr. 4 pagina's 199-206
Jaar:
1980-11-01
Inhoud:
LxM(NCSe)2 M'(SCN)2(PPh3)2 [M=Co(II), Ni(II); M'=Hg(II), Cd(II), Zn(II); L=pyridine (py), 2,2'-bipyridyl (bipy); x=4, 2] have been synthesized. Elemental analysis, magnetic moment, electronic and infrared spectral and thermogravimetric studies indicate that these complexes are dinuclear. The total softness of M and M' in the complexed state have also been calculated to derive certain conclusions.