SYNTHESIS AND CHARACTERIZATION OF TWO NOVEL, NEST-SHAPED Mo-Cu-S CLUSTER COMPOUNDS, [MoOS3Cu3(Py)5X] (X = Br, I), AND THE SUBSTITUTION OF Mo-Cu-S CLUSTERS
Titel:
SYNTHESIS AND CHARACTERIZATION OF TWO NOVEL, NEST-SHAPED Mo-Cu-S CLUSTER COMPOUNDS, [MoOS3Cu3(Py)5X] (X = Br, I), AND THE SUBSTITUTION OF Mo-Cu-S CLUSTERS
Auteur:
Hongwei, Hou Xinquan, Xin Shaofang, Lu Xiaoxing, Huang Qiangjin, Wu
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 35 (1995) nr. 3-4 pagina's 299-306
Jaar:
1995-07-01
Inhoud:
The title compounds [MoOS3Cu3(Py)5Br] (3) and [MoOS3Cu3(Py)5I] (4) were obtained through the nest-shaped cluster [(n-Bu)4N]2[MoOS3Cu3BrCl2] (1) and twin-nest-shaped cluster [Et4N]4[Mo2Cu6S6O2Br2I4](2) by reacting with pyridine. They show nest-shaped skeletons, and are characterized structurally by single-crystal X-ray analysis. These are the first neutral nest-shaped Mo(W)-Cu(Ag)-S clusters.