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Details for article 5 of 116 found articles
| Title: |
A SYNTHESIS AND STRUCTURE OF A WATER-SOLUBLE TETRAPYRIDYLPORPHYRINATO TIN(IV) CHLORIDE |
| Author: |
Jiang, Jianzhuang Jin, Xianglin Li, Ce Gu, Zhennan |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 35 (1995) nr. 3-4 pages 313-318 |
| Year: |
1995-07-01 |
| Contents: |
The water-soluble octahedral tin(IV) porphyrin complex, SnCl2tpyp, was synthesized via reaction of H2tpyp with anhydrous SnCl2. The crystal structure of this complex has been determined at room temperature. The tin(IV) atom is coordinated by four nitrogen atoms in a square-planar fashion with an average Sn-Np bond distance of 2.081(9)Å, and the coordination sphere is completed by two axial chloro ligands with an average Sn-Cl bond distance of 2.435(5)Å, Cl-Sn-Cl = 180.0 (1)°. Crystal data: a = 12.385(12), b = 26.88(2), c = 14.882(9)Å, β = 94.16 (7)°, monoclinic, space group C2/c, V = 4941Å3, Z = 4, C46H48Cl2N8O6Sn, 2687 observed data, R = 0.085. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 5 of 116 found articles
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