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THE REACTIONS OF [MoCl(GeCl3)(CO)3(NCMe)2] WITH NEUTRAL BI- AND TERDENTATE DONOR LIGANDS
Titel:
THE REACTIONS OF [MoCl(GeCl3)(CO)3(NCMe)2] WITH NEUTRAL BI- AND TERDENTATE DONOR LIGANDS
Auteur:
Baker, Paul K. Kendrick, Dafydd ap
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 30 (1993) nr. 3-4 pagina's 305-309
Jaar:
1993-12-01
Inhoud:
The reaction of [MoCl(GeCl3)(CO)3(NCMe)2] with an equimolar quantity of LˆL {LˆL = 2,2'-bipy, 1,10-phen, Ph2P(CH2)nPPh2 (n = 1 or 2)} in CH2Cl2 at room temperature gave either [MoCl(GeCl3)(CO)3(LˆL)] (LˆL = 2,2'-bipy or 1,10-phen) (1 and 2) or [MoCl(GeCl3)(CO)2 (NCMe)(LˆL)]{LˆL = Ph2P(CH2)nPPh2 (n = 1 or 2) (3 or 4), respectively. Equimolar quantities of [MoCl(GeCl3)(CO)2(NCMe){Ph2P(CH2)PPh2}] (3) and LˆL {LˆL = 2,2'-bipy or Ph2P(CH)2PPh2} react in CH2Cl2 at room temperature to afford the cationic complexes [Mo(GeCl3)(CO)2{Ph2P(CH2) PPh2}(LˆL)]Cl (5 and 6) in good yield. The cationic nature of 6 was established by chloride exchange by reacting Na[BPh4] with 6 in acetonitrile to give the tetraphenylborate complex [Mo(GeCl3)(CO)2{Ph2P(CH2)PPh2}2][BPh4] (7). Reaction of equimolar quantities of [MoCl(GeCl3) (CO)3(NCMe)2] and PhP(CH2CH2PPh2)2 in CH2Cl2 at room temperature afforded the dicarbonyl complex [MoCl(GeCl3)(CO)2{PhP(CH2CH2PPh2)2}] (8) in good yield.
Uitgever:
Taylor & Francis
Bronbestand:
Elektronische Wetenschappelijke Tijdschriften
Details van artikel 111 van 116 gevonden artikelen
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