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Details for article 3 of 23 found articles
| Title: |
Hydrothermal synthesis and crystal structures of two new divalent metal phosphonates with layered structure |
| Author: |
Meng, Lei Sun, Zhengang Dong, Dapeng Chen, Hui Zhu, Yanyu Zhang, Jing Zhao, Yan You, Wansheng |
| Appeared in: |
Journal of coordination chemistry |
| Paging: | Volume 60 (2007) nr. 19 pages 2075-2083 |
| Year: |
2007-10 |
| Contents: |
Two divalent metal phosphonates with a layered structure, Zn(H2L) (1) and Cd2L (2) (H4L = CH3CH2CH2N(CH2PO3H2)2), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction as well as with infrared spectroscopy, elemental analysis and thermogravimetric analysis. The structure of 1 shows a layered structure in which the 1D zinc(II) phosphonate chains are interconnected by bridging organic groups to form 2D layers. In 2, the interconnection of [CdO5N] and [CdO5] polyhedra via edge-sharing forms a dimer. The dimers are interconected by [CPO3] tetrahedra via corner-sharing to form 2D double layers in the bc-plane. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 3 of 23 found articles
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