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                                       Details for article 62 of 71 found articles
 
 
  Synthesis, structure and luminescent property of a novel Ag(I) complex: [Cu(pn)2][Ag3(CN)5]
 
 
Title: Synthesis, structure and luminescent property of a novel Ag(I) complex: [Cu(pn)2][Ag3(CN)5]
Author: Wang, Jiang-Yun
Zhang, Li-Zhi
Gu, Wen
Liu, Xin
Wang, Wen-Zhen
Liao, Dai-Zheng
Appeared in: Journal of coordination chemistry
Paging: Volume 59 (2006) nr. 15 pages 1685-1691
Year: 2006-10-15
Contents: Assembly of [Ag(CN)2]- units with diaminecopper(II) cation [Cu(pn)2]2+ (pn = 1,3-diaminopropane), gives the ionic complex [Cu(pn)2][Ag3(CN)5]. Single crystal X-ray analysis shows that this complex crystallizes in the triclinic, space group  [image omitted], a = 7.675(3), b = 8.707(4), c = 8.807(4) Å, α = 66.624(7), β = 67.045(7), γ = 79.179(7)°, Z = 1. The whole complex has 3D architecture through metal-metal interactions and other weak interactions. The complex displays weak luminescence determined by argentophilicity at room temperature in the solid state.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details for article 62 of 71 found articles
 
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