THE STRUCTURE OF DICHLOROBIS-1, 10-PHENANTHROLINE MANGANESE(II)
Titel:
THE STRUCTURE OF DICHLOROBIS-1, 10-PHENANTHROLINE MANGANESE(II)
Auteur:
Malinowski, Tadeusz J. Kravtsov, Victor Ch. Simonov, Yurii A. Lipkowski, Janusz Bologa, Olga. A.
Verschenen in:
Journal of coordination chemistry
Paginering:
Jaargang 37 (1996) nr. 1-4 pagina's 187-193
Jaar:
1996-02-01
Inhoud:
The preparation and characterization of the title complex, [Mn(Phen)2Cl2] are reported. The crystal structure determination shows that the two 1,10-phenanthroline ligands and two Cl-atoms form the pyramidally distorted octahedron around Mn(II). The chemically equivalent ligands play a different structural role in this complex. Crystals of [Mn(Phen)2Cl2] are monoclinic, space group P21/a with unit cell dimensions a = 14.522(4), b = 15.205(2), c = 9.470(1)Å, β = 98.90(2)°, V = 2065.9(7)Å3, Z = 4. The structure was refined by a full-matrix least-squares procedure to R = 0.043 for 2783 observed reflections.