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| Titel: |
COPPER(II) COORDINATION COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA II. MONONUCLEAR-, HEXA-, HEPTA-AND OCTACOORDINATE COMPOUNDS |
| Auteur: |
Melnik, Milan Kabesova, Maria Macaskova, Lubov Holloway, Clive E. |
| Verschenen in: |
Journal of coordination chemistry |
| Paginering: | Jaargang 45 (1998) nr. 1-4 pagina's 31-145 |
| Jaar: |
1998-10-01 |
| Inhoud: |
This review summarizes the data for over five hundred and fifty six-, seven- and eight-coordinate Cu(II) coordination compounds. The six-coordinate derivatives are mostly distorted tetragonal (elongation along a single C4 axis). The seven-coordinate derivatives are only penta-gonal-bipyramidal with different degrees of distortion and the eight-coordinate complexes are dodecahedral. The most common ligands are O- and N-donors. There is a trend for the Cu-L distance to increase with covalent radius of the coordinated atom and also increasing coordination number. In general, Cu(II) compounds “prefer” a monoclinic class and are blue or green. Several relationships were found and discussed. The data are compared and discussed with those of four- and five-coordinate Cu(II) compounds. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 11 van 73 gevonden artikelen
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