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Details for article 17 of 178 found articles
| Title: |
1,4-Anhydro-2,3,6-Tri-O-Methyl-D-Glucitol Formed as an Artifact in the Reductive Cleavage of Permethylated 1,4-Linked Glucopyranosides |
| Author: |
Bennek, John A. Rolf, David Gray, Gary R. |
| Appeared in: |
Journal of carbohydrate chemistry |
| Paging: | Volume 2 (1983) nr. 4 pages 385-393 |
| Year: |
1983 |
| Contents: |
1,5-Anhydro-2,3,6-tri-O-methyl-d-glucitol (1) is formed as the major product in the reductive cleavage of permethylated 4-linked glucopyranosyl residues, but a small amount of 1,4-anhydro-2,3,6-tri-O-methyl-d-glucitol (2) is formed as an artifact when water is present. The formation of 2 can be minimized by carrying out the reductive cleavage under anhydrous conditions. The independent synthesis of 2 and its 5-O-acetyl derivative (4) is described. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 17 of 178 found articles
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