|
| << previous | next >> |
Journal description
All volumes of the corresponding journal
All issues of the corresponding volume
All articles of the corresponding issues
Details for article 99 of 252 found articles
| Title: |
Kinetics of the Oxidation of Monosaccharides with Bromamide-T |
| Author: |
Kiviniemi, Anne-Marja Tomperi, Paivi Virtanen, Pentti O. I. |
| Appeared in: |
Journal of carbohydrate chemistry |
| Paging: | Volume 13 (1994) nr. 3 pages 457-463 |
| Year: |
1994-04-01 |
| Contents: |
The kinetics of the reaction of eight monosaccharides and the model compound acetoin with sodium salt of N-bromo-p-toluenesulfonamide in hydrochloric acid solutions was studied at 25 °C. The low value of the ratio of the second-order rate constants k2 (Acetoin)/k2 (Glucose) and the low reactivity of ketosugars relative to that of aldosugars indicate that the ring forms of the aldosugars are involved in the oxidations. A mechanism consistent with the experimental observations is proposed. The configurations and reactivities of aldosugars are compared. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 99 of 252 found articles
| << previous | next >> |