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                                       Details for article 180 of 252 found articles
 
 
  Synthesis of a Site-Specific Deuterium Substituted Methyl β-D-Glucan Decasaccharide
 
 
Title: Synthesis of a Site-Specific Deuterium Substituted Methyl β-D-Glucan Decasaccharide
Author: Hallgren, Christer
Widmalm, Goran
Appeared in: Journal of carbohydrate chemistry
Paging: Volume 12 (1993) nr. 3 pages 309-333
Year: 1993-04-01
Contents: Synthesis of a (β-D-glucan decasaccharide, with alternating (β-1,3 and (β-1,4-linkages, is described. The decasaccharide is fully C-deuterated except for the central cellobiose residue. The main glycosylation methods used were activation of glycosyl bromides with silver triflate or activation of thioglycosides with dimethyl(methylthio)sulfonium triflate (DMTST). In order to establish the anomeric configuration of the various oligosaccharide derivatives, a fully C-protonated decasaccharide was also synthesized by a parallel route.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details for article 180 of 252 found articles
 
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