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                                       Details for article 169 of 252 found articles
 
 
  Synthesis and Stereochemistry of Some new Derivatives of 1,2-O-Cyclohexylidene-α-D-Xylofuranuronic Acid
 
 
Title: Synthesis and Stereochemistry of Some new Derivatives of 1,2-O-Cyclohexylidene-α-D-Xylofuranuronic Acid
Author: Miljkovic, Dusan
Vukojevic, Nada
Minie, DuSAn
Hadzˆc, Pavle
Hajdukovic, Gordana
Appeared in: Journal of carbohydrate chemistry
Paging: Volume 6 (1987) nr. 3 pages 501-508
Year: 1987-09-01
Contents: 1,2-O-Cyclohexylidene-α-d-xylofuranuronic acid (2) has been converted into its 3-O-acetyl derivative and consecutively to the corresponding acid chloride and ethyl ester. Direct reaction of 2 with ethanol in the presence of p-to-luene sulphonic acid gave the ethyl ester. Reaction of 2 with phosphorus pentachloride in dry ether gave the acid chloride of 1,2-O-cyclohexylidene-3-O-dichlorophosphoryl-α-d-xylofuranuronic acid. Conformational data have been obtained from 1H and 13C NMR measurements.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details for article 169 of 252 found articles
 
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