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Details for article 156 of 252 found articles
| Title: |
Syntheses of 4, 5-Di-O-bexzyl-2-deoxy-2-C-methyl L-lyxose and Methyl 4, 5-Di-O-bexzyl-2-deoxy-2-C-methyl-3-O-metkyl-L-lyxonate |
| Author: |
Tadano, Kin-Ichi Iimura, Youichi Suami, Tetsuo |
| Appeared in: |
Journal of carbohydrate chemistry |
| Paging: | Volume 5 (1986) nr. 3 pages 411-422 |
| Year: |
1986-09-01 |
| Contents: |
The title compounds, which possess C-methyl groups at the α-position of carbonyl groups and vicinal hydroxyl groups with syn (three) relationship, were synthesized efficiently from known 3-decxy-1, 2-O-isopropylidene-3-C-methyl-α-D-allofuranose. The synthetic routes involve: 1) inversion of C-5 configuration of the starting sugar, 2) suitable protection of the 5, 6-diol, and 3) glycol cleavage of the 1, 2-diol to an aldehyde or direct oxidation of the diol to carboxylic acid. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 156 of 252 found articles
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