Preparation and Properties of Polyether Scale Inhibitor Containing Fluorescent Groups
Titel:
Preparation and Properties of Polyether Scale Inhibitor Containing Fluorescent Groups
Auteur:
Du, Kun Zhou, Yuming Dai, Liya Wang, Yingying
Verschenen in:
International journal of polymeric materials
Paginering:
Jaargang 57 (2008) nr. 8 pagina's 785-796
Jaar:
2008-08
Inhoud:
Water soluble fluorescent monomer, 8-allyloxy-1,3,6-pyrenetrisulfonic acid trisodium salt (AP), was synthesized from 8-hydroxy-1,3,6-pyrenetrisulfonic acid trisodium salt and allyl chloride. AP-tagged copolymer maleic anhydride (MA)-ammonium allyl polyethoxy sulfate (APES)-AP, which is a calcium phosphate inhibitor, was prepared and the structures of AP and MA-APES-AP were characterized by FTIR and 1H-NMR. The influence of the mole ratio of MA:APES on a calcium phosphate inhibitor of MA-APES-AP was discussed. Fluorescent properties and scale inhibition performance of MA-APES-AP were also studied. The results indicate that monomer ratio has great impact on the performance of MA-APES-AP. Fluorescent intensity increases with the concentration of MA-APES-AP, with a correlation coefficient (r) of 0.9934 and MA-APES-AP limit of detection of 1.72 mg · L-1. Calcium phosphate inhibition performance test results show that calcium phosphate inhibition of MA-APES-AP reaches 98.78 percent when the dosage is 12 mg · L-1 at 80°C.