Digitale Bibliotheek
Sluiten Bladeren door artikelen uit een tijdschrift
 
<< vorige    volgende >>
     Tijdschrift beschrijving
       Alle jaargangen van het bijbehorende tijdschrift
         Alle afleveringen van het bijbehorende jaargang
           Alle artikelen van de bijbehorende aflevering
                                       Details van artikel 3 van 5 gevonden artikelen
 
 
  Intrinsic Viscosity Characterization of Poly(cis-isoprene) in Hevea Natural Rubber
 
 
Titel: Intrinsic Viscosity Characterization of Poly(cis-isoprene) in Hevea Natural Rubber
Auteur: Bonfils, Frederic
Char, Christine
Ehabe, Eugene E.
Verschenen in: International journal of polymeric materials
Paginering: Jaargang 57 (2008) nr. 11 pagina's 1036-1044
Jaar: 2008-11
Inhoud: Intrinsic viscosity [η] characterizes flow, polymerization, or degradation of dilute polymer solutions. Unlike other high polymers, natural rubber hardly completely dissolves in most organic solvents, and eliminating the insoluble phase undermines the quality of the measurement and its interpretation. On using some natural and synthetic polyisoprene samples, the Huggins and Schulz-Blaschke best-fits were most suitable for estimating [η] for very dilute polyisoprene solutions (< 0.06 g/dL in cyclohexane at 30°C). Logarithmic linearization of the Mark-Houwink-Sakurada equation ([η] = K.Ma; M is molar mass) and a curvilinear model on untransformed data gave different Mark-Houwink constants (K and a) for polyisoprene standards, differences that seemed to have no bearing on their viscosity-average molar masses ([image omitted]). Plots of [image omitted] against weight-average molar mass enabled differentiation of the polyisoprenes into larger groupings, differences that could be attributed to different extents of branching or of aggregation between macromolecules.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

                             Details van artikel 3 van 5 gevonden artikelen
 
<< vorige    volgende >>
 
 Koninklijke Bibliotheek - Nationale Bibliotheek van Nederland