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                                       Details for article 1 of 7 found articles
 
 
  ARYLENECYCLOSILOXANE-DIMETHYLSILOXANE COPOLYMERS
 
 
Title: ARYLENECYCLOSILOXANE-DIMETHYLSILOXANE COPOLYMERS
Author: Mukbaniani, O. V.
Karchkhadze, M. G.
Khananashvili, L. M.
Koiava, N. A.
Appeared in: International journal of polymeric materials
Paging: Volume 52 (2003) nr. 10 pages 877-889
Year: 2003-10
Contents: The reaction of heterofunctional condensation (HFC) of 1,4-bis(phenyldichlorosilyl)benzene with dihydroxydiphenylsilane at initial ratio of 1:4, led to tetrakis(hydroxydiphenylsiloxy)-1,4-bis(phenylsilyl)benzene. By heterofunctional condensation of the tetrakis(hydroxydiphenylsiloxy)-1,4-bis(phenylsilyl)benzene with organotrichlorosilanes at 1:2 ratio dichloro-containing arylenecyclosiloxanes were obtained. The dichloroarylenecyclosiloxanes has been obtained by successive heterofunctional condensation of 1,4-bis(dichlorophenylsilyl)benzene with dihydroxydiphenylsilane and organotrichlorosilanes at 1:4:2 ratio. By hydrolysis of dichloroarylenecyclosiloxanes in neutral condition the corresponding dihydroxy compounds were obtained. By heterofunctional polycondensation of dichloro(dihydroxy)arylenecyclosiloxanes with α, s-dihydroxy (bisdimethylamino)dimethylsiloxanes arylenecyclosiloxane-dimethylsiloxane copolymers were obtained. Thermogravimetric, thermomechanical and X-ray investigations of the synthesized copolymers have been carried out.
Publisher: Taylor & Francis
Source file: Elektronische Wetenschappelijke Tijdschriften
 
 

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