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  Thermoplastic Elastomers 4. Poly(ether-ester-imide)s Derived from Trimellitic Anhydride, 1,6 Diaminohexane,1,4-Dihydroxybutane and Poly(ethylene oxide)
 
 
Titel: Thermoplastic Elastomers 4. Poly(ether-ester-imide)s Derived from Trimellitic Anhydride, 1,6 Diaminohexane,1,4-Dihydroxybutane and Poly(ethylene oxide)
Auteur: Kricheldorf, H. R.
Wollheima, T.
Soliman, M.
Buning, G. H. Werumeus
Koning, C. E.
Altstadt, V.
Verschenen in: International journal of polymeric materials
Paginering: Jaargang 50 (2001) nr. 3-4 pagina's 359-372
Jaar: 2001-10-01
Inhoud: Four thermoplastic elastomers having the structure of poly(ether-ester-imide)s, PEEIs, were prepared and characterized. The hard segments were synthesized from 1,4-dihydroxybutane and from an imide dicarboxylic acid based on 1,6-diaminohexane and trimellitic anhydride. Poly(tetramethylene oxide)-1000, poly(ethylene oxide)-1000 or mixtures of both oligoethers served as soft segments. The PEEI based on neat PEO-1000 was also modified by a solid state post-condensation which raised the nrel value by a factor three. All PEEIs were characterized by H NMR spectroscopy, inherent viscosity and DSC measurements, and stress-strain measurements. The PEEIs based on neat PEO-1000 were also characterized by dynamic thermal mechanical analysis, by hysteresis measurements and by melt rheology.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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