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Details van artikel 14 van 17 gevonden artikelen
| Titel: |
Synthesis of PET-based Liquid Crystalline Copolyesters: Influence of the Overall Degree of Aromaticity on Phase Segregation |
| Auteur: |
Minkova, Liliya I. Milie, Rossana Filippi, Sara Polacco, Giovanni |
| Verschenen in: |
International journal of polymeric materials |
| Paginering: | Jaargang 50 (2001) nr. 3-4 pagina's 373-386 |
| Jaar: |
2001-10-01 |
| Inhoud: |
Novel PET-based copolyesters have been synthesised by transesterification of PET with equimolar amounts of sebacic acid (S) and 4,4'-diacetoxybiphenyl (B) and with varying amounts of 4-acetoxybenzoic acid (H). The structure, the morphology, and the thermal properties of the PET-S-B-H copolyesters have been studied by scanning electron microscopy (SEM), polarized optical microscopy (POM), differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXS). It has been demonstrated that segregation of a liquid-crystalline phase, during polycondensation, provides the driving force for compositional differentiation, with the result that the final products are “synthetic polymer blends”. The characteristics of PET-S-B-H copolymers have been compared with those of PET-S-Q-H copolyesters having the same molar composition (Q-hydroquinone). It has been shown that the phase segregation is more prominent in PET-S-B-H copolyesters than in PET-S-Q-H polymers of similar molar composition. The influence of the overall degree of aromaticity of the copolyester on the segregation phenomenon has been discussed. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 14 van 17 gevonden artikelen
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