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                                       Details van artikel 7 van 10 gevonden artikelen
 
 
  PhaseTransfer Catalysis in Polycondensation Processes. XXI. Molecular Modeling and Thermal Behaviour of Some Aromatic Polyethers Containing Oxetanic Rings in the Main Chain
 
 
Titel: PhaseTransfer Catalysis in Polycondensation Processes. XXI. Molecular Modeling and Thermal Behaviour of Some Aromatic Polyethers Containing Oxetanic Rings in the Main Chain
Auteur: Scutaru, D.
Hurduc, N.
Creanga, A.
Hurduc, N.
Ghirvu, C.
Verschenen in: International journal of polymeric materials
Paginering: Jaargang 43 (1999) nr. 3-4 pagina's 293-300
Jaar: 1999-05-01
Inhoud: The paper studies the correlation between the structure and the thermal properties of some polyethers, using molecular simulation as a complementary method. The polymers were synthesized by phase transfer catalysis, starting from 3,3-bis(chloromethyl)oxetane and various bisphenols, as follows: 4,4'-dihydroxydiphenyl, bisphenol A, 4,4'-dihydroxy-diphenylmethane, 1,1 -bis-(4-hydroxyphenyl)ethane, 1,1 -bis-(4-hydroxyphenyl)cydo-hexane, 2,2-bis-(3'-methyl-4'-hydroxyphenyl)propane. 4,4'-dihydroxy-diphenylether, 4,4'-dihydroxydiphenyl-(1,2-ethane). The polyethers were characterized by thermogravi-metric methods and different scanning calorimetry. Molecular simulations were performed using a force-field program HYPERCHEM (version 4.5). This study permitted to select the most recommended structures for a subsequent cross-linking process.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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