Synthesis and Investigation of Properties of the Optically Transparent Carbochain Copolymers with Elementorganical and Hydroxy Groups in the Side Chain of Macromolecules
Titel:
Synthesis and Investigation of Properties of the Optically Transparent Carbochain Copolymers with Elementorganical and Hydroxy Groups in the Side Chain of Macromolecules
Auteur:
Lekishvili, N. Asatiani, L. Andguladze, N. Lekishvili, G. Guliashvili, T.
Verschenen in:
International journal of polymeric materials
Paginering:
Jaargang 39 (1998) nr. 3-4 pagina's 237-253
Jaar:
1998-02-01
Inhoud:
The carbochain co-polymers with elementorganical and hydroxy groups in the side chain of macromolecules have been synthesized. The reactions of the radical co-polymerization of perfluoroalkyl(meth)acrylates and siliconorganic methacrylates with dimethylvinylacetylenylcarbinol in mass were studied. By using NMR-1H spectroscopy of high resolution, UV, IR spectroscopy and GLC methods the structure and the composition of co-polymers, constants of copolymerization rijrji, the distribution of homo and heterodiads in macromolecular chain of the co-polymers were determined. The optical, thermomechanical properties and the thermooxidative stability of the co-polymers were researched. The possibility of their application for production of the optical adhesives was determined.