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| Titel: |
Kinetics of the Three-Dimensional Thermopolymerization |
| Auteur: |
Medvedevskikh, Ju. G. Zahladko, E. A. Turovski, A. A. Zaikov, G. E. |
| Verschenen in: |
International journal of polymeric materials |
| Paginering: | Jaargang 38 (1997) nr. 3-4 pagina's 329-337 |
| Jaar: |
1997-12-01 |
| Inhoud: |
A kinetic model of the three-dimensional radical polymerization of oligomers bulk is proposed. The presented analysis shows that the proposed equation agrees with the known experimental kinetic data of the three-dimensional polymerization. The construction of the equation is based on the concept of the microheterogenous model and the postulate that the rate of the three-dimensional polymerization is the sum of the rates of the homophase processes, which run in various phases and interphases, and that the initiator is distributed uniformly between the phases and interphase layer. The clusters of the solid polymer in liquid oligomer phase and clusters of the liquid oligomer in solid polymer matrix are assumed to have the fractal structure. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 6 van 12 gevonden artikelen
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