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Details for article 3 of 10 found articles
| Title: |
Fractal Kinetics of the Oxidation of Aliphatic Polyamides |
| Author: |
Postnikov, L. M. Vinogradov, A. V. |
| Appeared in: |
International journal of polymeric materials |
| Paging: | Volume 38 (1997) nr. 1-2 pages 79-98 |
| Year: |
1997-11-01 |
| Contents: |
Analysis of reactions kinetics in solid polymers requires a consideration of structural inhomogeneity of different levels and transport retardation of active particles peculiar to polymers. However, for multi-step reactions this problem may be only posed after sufficiently comprehensive description of their specific mechanism representing the balance of separate steps correlation. The kinetic justification of a new mechanism of aliphatic polyamides photooxidation that was completed recently makes this possible. Sufficient extending of measured rates diapason to the post-effect area of UV-irradiation allows to estimate correlation of homogeneous and inhomogeneous factors of this process in the context of fractal kinetic model. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 3 of 10 found articles
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