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Details for article 1 of 10 found articles
| Title: |
Divinyl Polymerization of N, N'-Methylenebisacrylamide Initiated by Peroxydisulphate-Thiomalic Acid Redox System |
| Author: |
Rathinamuthu, K. Victoria, R. Vaidyanathan, S. Gopaland, A. |
| Appeared in: |
International journal of polymeric materials |
| Paging: | Volume 38 (1997) nr. 1-2 pages 49-64 |
| Year: |
1997-11-01 |
| Contents: |
The kinetics of polymerization of N,N'-methylenebisacrylamide (MBA), a symmetrical non-conjugated divinyl monomer, initiated by a redox system potassium peroxydisulphate (PDS)-thiomalic acid (TMA) was studied in aqueous medium in the temperature range 35-50 °C. Rate of polymerization (Rp) and rate of disappearance of peroxydisulphate (—RPDS) were followed. From the rate law for polymerization, a mechanism was proposed incorporating cyclopolymerization in the propagation in contrast to normal propagation in monovinyl polymerization. Rate parameters were evaluated and its significance discussed. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 1 of 10 found articles
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