Experimental Methods for Estimating Stabilizers' Efficiency
Titel:
Experimental Methods for Estimating Stabilizers' Efficiency
Auteur:
Gurvich, Ya. A. Arzamanova, I. G. Zaikov, G. E.
Verschenen in:
International journal of polymeric materials
Paginering:
Jaargang 31 (1996) nr. 1-4 pagina's 95-118
Jaar:
1996-01-01
Inhoud:
Experimental methods for estimating the efficiency of stabilizers of various classes-phenols, amines, phosphites etc.-in various model systems both on the base of polymer and without polymer (low molecular) are described. The large experimental material considered is obtained with the help of various physicochemical methods: manometry, spectroscopy, DTA, calorimetry, chemiluminescence, viscosimetry, polarography etc. Determination of regularities in changes of efficiency of stabilizers characterized by various structures and reactivities allows us to choose the most promising ones for practical use and to look for new active stabilizers more reasonably and purposefully. The elaboration of a mathematical model of the oxidation process permits the creation of the base for semi-empirical forecast of the stabilizer properties.