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| Titel: |
Dynamic Mechanical Properties of Carbon Black Filled Ethylene Vinyl Acetate Rubber |
| Auteur: |
Mukhopadhyay, K. Tripathy, D. K. De, S. K. |
| Verschenen in: |
International journal of polymeric materials |
| Paginering: | Jaargang 20 (1993) nr. 3-4 pagina's 117-132 |
| Jaar: |
1993 |
| Inhoud: |
The dynamic mechanical properties of ethylene vinyl acetate (EVA) rubber filled with different loadings of carbon black and at different degrees of crosslinking were studied over a wide range of temperatures (-150° to +200°C). The loss tangent (tan δ) versus temperature plots indicated presence of different transitions. The α-transition (or the glass-rubber transition) corresponding to the maximum in tan δ value, occurred at -17°C, which is the principal glass-transition temperature (abbreviated as Tg) of EVA rubber. The γ-transition occurred in the temperature region of -125° to -135°C, while the β-transition appeared as a shoulder in the temperature region of -65° to -75°C. Besides, there was also a high tempeature transition around +62°C which is known as liquid to liquid transition (T1.1). Incorporation of carbon black filler did not cause any shift of Tg, while the tan δ peak values at Tg decreased sequentially with increase in filler loading. The γ- and β-relaxations were found to be insensitive to filler loading. The T1.1 transition, however, was found to be suppressed by incorporation of carbon black filler particularly at high loading. Extent of crosslinking did not influence the Tg But, the T1.1 transition, which was prominent with the lightly crosslinked system was found to be suppressed at high level of crosslinking. Strain dependent dynamic mechanical properties under isothermal conditions showed that the secondary structure breakdown of carbon black filler under the effect of strain amplitude is influenced by the degree of crosslinking of EVA rubber. |
| Uitgever: |
Taylor & Francis |
| Bronbestand: |
Elektronische Wetenschappelijke Tijdschriften |
Details van artikel 3 van 19 gevonden artikelen
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