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Details for article 11 of 27 found articles
| Title: |
Kinetics and Mechanism of Oxidation of Mono- and Polyacetals |
| Author: |
Rakhmankulov, D. L. Zlotsky, S. S. Kuramshin, E. M. Kulak, L. G. |
| Appeared in: |
International journal of polymeric materials |
| Paging: | Volume 13 (1990) nr. 1-4 pages 113-122 |
| Year: |
1990-09-01 |
| Contents: |
Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15-16 hr) leads to the formation monoethers of the corresponding glycols with 68-90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 11 of 27 found articles
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