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Details for article 28 of 31 found articles
| Title: |
The effect of pressure on rates of some catalysed Diels-Alder reactions |
| Author: |
Isaacs, Neil S. Maksimovic, Ljiliana Laila, Abdulhameed |
| Appeared in: |
High pressure research |
| Paging: | Volume 13 (1994) nr. 1-3 pages 21-27 |
| Year: |
1994-11-01 |
| Contents: |
The Diels-Alder reactions between isoprene and N-phenylmaleimide catalysed by Lewis acids, in particular by aluminium chloride and by lithium perchlorate, have volumes of activation more negative than does the uncatalysed reaction. That between 9-anthracenemethanol and N-ethylmaleimide, is faster in water than in organic solvents and has a slightly more negative volume of activation in the aqueous medium than in organic. The significance of these measurements is discussed. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 28 of 31 found articles
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