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Details for article 32 of 41 found articles
| Title: |
Some Aspects of Aprotic Copper(I)-Dioxygen Systems |
| Author: |
Vies, Geoffrey Da El-sayed, Mohamed A. |
| Appeared in: |
Comments on inorganic chemistry |
| Paging: | Volume 4 (1985) nr. 3 pages 151-162 |
| Year: |
1985-07-01 |
| Contents: |
There has been considerable progress in understanding the stoichiometry, products and kinetics of aprotic copper(I)-dioxygen reactions, which are an integral part of all copper-catalyzed dioxygen systems. Attention is focused on the effects of ligands on the reaction stoichiometry and on the stability of the products. The great tendency for complete aprotic dioxygen reduction appears to have both kinetic and thermodynamic origins. It is suggested that immobilization of copper(I) sites is necessary to prevent complete aprotic reduction of dioxygen. |
| Publisher: |
Taylor & Francis |
| Source file: |
Elektronische Wetenschappelijke Tijdschriften |
Details for article 32 of 41 found articles
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