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                                       Details van artikel 6 van 9 gevonden artikelen
 
 
  Effect of polymorphic phase transformations in alumina layer on ignition of aluminium particles
 
 
Titel: Effect of polymorphic phase transformations in alumina layer on ignition of aluminium particles
Auteur: Trunov, M. A.
Schoenitz, M.
Dreizin, E. L.
Verschenen in: Combustion theory and modelling
Paginering: Jaargang 10 (2006) nr. 4 pagina's 603-623
Jaar: 2006-08-01
Inhoud: The mechanism of aluminium oxidation is quantified and a simplified ignition model is developed. The model describes ignition of an aluminium particle inserted in a hot oxygenated gas environment: a scenario similar to the particle ignition in a reflected shock in a shock tube experiment. The model treats heterogeneous oxidation as an exothermic process leading to ignition. The ignition is assumed to occur when the particle's temperature exceeds the alumina melting point. The model analyses processes of simultaneous growth and phase transformations in the oxide scale. Kinetic parameters for both direct oxidative growth and phase transformations are determined from thermal analysis. Additional assumptions about oxidation rates are made to account for discontinuities produced in the oxide scale as a result of increase in its density caused by the polymorphic phase changes. The model predicts that particles of different sizes ignite at different environment temperatures. Generally, finer particles ignite at lower temperatures. The model consistently interprets a wide range of the previously published experimental data describing aluminium ignition.
Uitgever: Taylor & Francis
Bronbestand: Elektronische Wetenschappelijke Tijdschriften
 
 

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